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Understanding cenros Error

An my "easy" but not very useful answer is that this particular subset
probably violates some assumption of the cenros() model. I myself would
start with simple inspections of the data, such as

  with( subset(chem, param=='Ag'),  table(ceneq1) )
  with( subset(chem, param=='Ag'), qqnorm(quant) )
  with( subset(chem, param=='Ag'), range(quant) )


in the hopes that something pops out.

Do you have any zeros in quant?  (see ?cenros)

-Don